3/16/10 Mr. Min Li chemical equilibrium: Le Chateliers Principle and Measurement of Equilibrium constant 1. Does the deliberate fender subject of the ortho orthophosphate fan ascertain with your inquireations? Why or why not? (In other words, prevail the expected pilot program capacity of the fender establish on the flesh of moles of HPO42- in the damp and equality this to the measured buffer capacity.) Yes, I felt that the buffer did thusly decent my expectations. The buffer capacity based on the number of moles of HPO42- is 3.63. Buffers is approximately effective when the pH=pKa ± 1.0. 2. What do you expect would be the buffer capacity of the phosphate buffer for intake of NaOH? Explain. I expect the buffer capacity of the phosphate buffer for consumption of NaOH is 4.95. The pH of the solution was 5.25 and by using the relationship of pH and pKa (pH = pKa + logarithm ([A-]/[HA])) I was able to get the buffer capacity. The buffer checks surface because pH=pKa ± 1.0. Results: Phosphate buffer: The initial pH for the phosphate buffer is 6.83 and it takes 18 drops to equal 1.0 mL of 1.0 M HCl.
The account book of HCl required to break the buffer was 1mL, and the known tightfistedness of the HCl 1.0 M The number of moles of HCl consumed by the buffer was 0.02. [pic] Acetate buffer: The guide pH of NaCH3CO2 was 5.25 and the actual measured pH for the acetate rayon rayon buffer was 11.21. The number of drops to equal 1Ml of NaOH is 17 drops. To reach the pH the 7, 2.4mL of NaOH was added to the solution. The great deal of NaOH required to break th e buffer is 2mL, and the concentration of Na! OH was , calculate and composing the number of moles of NaOH consumed by the buffer was .02. This is the buffer capacity of the acetate buffer to consume NaOH reaches 7.0. [pic]If you want to get a unspoilt essay, order it on our website: BestEssayCheap.com
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